There are many resources available to those who are interested in beginning to homeschool. But having just done a google search on "start homeschooling", I do not see that any other resource presents the diversity of personal experiences found at Spunky's Online Homeschool Convention. Over 50 entries present their family's experiences with homeschooling and I have found it very interesting and informative.
My main advice for those who are just starting out is this: realize that there is much information available but do not let yourself get overwhelmed. Eventually, your focus will narrow and you will find the approach and resources best for you. Just keep an open mind and keep investigating your options until you discover what is best for you and your family.
Most of all, as a new homeschooler, I have found the moms who have homeschool blogs to be very helpful and responsive. If you have any questions, you should feel free to contact any of us.